Tundup, Tsering (2022) Visible-light mediated trifluoromethylation followed by alkylation of unactivated alkenes. Masters thesis, Indian Institute of Science Education and Research Kolkata.
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Text (MS dissertation of Tsering Tundup (17MS199))
17MS199_Thesis_file.pdf - Submitted Version Restricted to Repository staff only Download (4MB) |
Abstract
In this course of work, we have developed a novel approach for an efficient, mild, and transition metal-free visible-light-induced three-component trifluoromethylation of unactivated alkenes followed by alkylation, allowing the formation of a new C(sp³)−C(sp³) and C(sp³)−CF₃ bonds. We employed a bench stable, cheap, and easily handled Langlois reagent as CF3 source and Michael acceptor as an alkylating reagent in our protocol. In this methodology, we have tested various Michael acceptors and unactive alkenes to furnish our desired products with excellent yield and high chemo-selectivity.
| Item Type: | Thesis (Masters) |
|---|---|
| Additional Information: | Supervisor: Dr. Devarajulu Sureshkumar |
| Uncontrolled Keywords: | Alkenes; Michael Acceptors; Photocatalysis; Photoredox Catalyst; Trifluoromethylation |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Department of Chemical Sciences |
| Depositing User: | IISER Kolkata Librarian |
| Date Deposited: | 16 Oct 2023 10:59 |
| Last Modified: | 16 Oct 2023 10:59 |
| URI: | http://eprints.iiserkol.ac.in/id/eprint/1427 |
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