Mall, Utkarsh (2021) Pathway Complexity in Presence of Anticooperative Interactions. Masters thesis, Indian Institute of Science Education and Research Kolkata.
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Text (MS Dissertation of Utkarsh Mall (16MS060))
16MS060_Thesis_file.pdf - Submitted Version Restricted to Repository staff only Download (1MB) |
Abstract
Understanding the formation of complex supramolecular self-assembly is needed to design and form supramolecular polymers with desired properties. In this project report, I examine the self-assembly behaviour of an L-Tyrosine Perylene bisimide (L-Tyr PBI). L-Tyr PBI exhibits two distinct chiral aggregates: a kinetic and a thermodynamic aggregate. These two aggregates, together with monomers, exhibit pathway complexity. The kinetic aggregate is an anti-cooperative aggregate that can be converted to the thermodynamic aggregate by selectively disrupting hydrogen bonding. The thermodynamic aggregate formed is an isodesmic aggregate.
| Item Type: | Thesis (Masters) |
|---|---|
| Additional Information: | Supervisor: Prof. Debansu Chaudhuri |
| Uncontrolled Keywords: | Pathway Complexity, Anticooperative Interactions, Complex Supramolecular, Isodesmic Aggregate |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Department of Chemical Sciences |
| Depositing User: | IISER Kolkata Librarian |
| Date Deposited: | 23 Sep 2025 10:41 |
| Last Modified: | 23 Sep 2025 10:41 |
| URI: | http://eprints.iiserkol.ac.in/id/eprint/1790 |
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