Synthesis of a Trianionic Porphyrinoid Amide Based Ligand and the corresponding Iron (II & III) and Ni(II)complexes

Ghosh, Sayanil (2025) Synthesis of a Trianionic Porphyrinoid Amide Based Ligand and the corresponding Iron (II & III) and Ni(II)complexes. Masters thesis, Indian Institute of Science Education and Research Kolkata.

Text (MS Dissertation of Sayanil Ghosh (23MP029)) 23MP029_Thesis_file.pdf - Submitted Version Restricted to Repository staff only Download (2MB)

Abstract

This work presents the synthesis and initial study of NTPA-based iron and NDPA-based nickel complexes. Moving forward, efforts will focus on isolating single crystals of both Fe(II) and Fe(III) NTPA species to enable detailed structural analysis. These data will be critical for understanding their coordination environments and informing further ligand design. Additionally, catalytic applications of the Ni-NDPA complexes will be explored, with emphasis on reactions involving redox activity or small molecule activation. The stability and modular nature of the ligand offer promising potential for developing efficient catalytic systems.

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