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Abnormal N-Heterocyclic Carbene Supported Palladacycle: Regioselective for Arylation of Heteroarenes via Decarboxylation

Jose, Anex (2017) Abnormal N-Heterocyclic Carbene Supported Palladacycle: Regioselective for Arylation of Heteroarenes via Decarboxylation. Masters thesis, Indian Institute of Science Education and Research Kolkata.

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    Abstract

    This thesis consists of synthesizing new abnormal N-heterocyclic carbene ligands and their palladium (II) complexes for decarboxylative C-C cross coupling reactions of N-methylindole-2-carboxylic acids with aryl halides. The thesis begins by discussing the importance of heteroaromatic biaryl compounds. The advantages of decarboxylative C-C coupling reaction over traditional cross-coupling reactions in synthesis of biaryl moieties, previous catalysis reports for C2-arylation of N-methylindoles via decarboxylative cross coupling as well as their limitations are briefly outlined. The motivation for doing this project and our objectives are delineated. Finally, our experimental results and future directions of the work are described.

    Item Type: Thesis (Masters)
    Additional Information: Supervisor: Dr. Swadhin K. Mandal
    Uncontrolled Keywords: Decarboxylation; N-Heterocyclic Carbene; Palladacycle
    Subjects: Q Science > QD Chemistry
    Divisions: Department of Chemical Sciences
    Depositing User: IISER Kolkata Librarian
    Date Deposited: 15 Nov 2017 17:07
    Last Modified: 15 Nov 2017 17:07
    URI: http://eprints.iiserkol.ac.in/id/eprint/583

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