Mandal, Ushnish (2016) Phenalenyl-Based Copper(II) Catalyst for Asymmetric Henry Reaction. Masters thesis, Indian Institute of Science Education and Research Kokata.
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PDF (MS dissertation of Ushnish Mandal (11MS081))
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Abstract
A new phenalenyl-based chiral ligand, 9-N-methylamino-1-N'-(S)-(-)-α-methylbenzylamino-phenalene, has been synthesized in high yield. The reaction of CuCl2 with chiral phenalenyl-based ligand, 9-N-methylamino-1-N'-(S)-(-)-α-methylbenzylamino-phenalene in 1:1 ratio results in the formation of chiral copper complex. That complex efficiently catalyzes the C-C bond forming Henry reaction, between nitroalkane and aldehydes, with high yields (up to 90%) and moderate enantioselectivites (up to 80%).
| Item Type: | Thesis (Masters) |
|---|---|
| Additional Information: | Supervisor: Dr. Swadhin K. Mandal |
| Uncontrolled Keywords: | Asymmetric Henry Reaction; Catalyst; Chiral Copper Complex; Chiral Ligand; Copper(II); Henry Reaction; Phenalenyl-Based Copper(II) |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Department of Chemical Sciences |
| Depositing User: | IISER Kolkata Librarian |
| Date Deposited: | 16 Aug 2016 07:14 |
| Last Modified: | 16 Aug 2016 07:14 |
| URI: | http://eprints.iiserkol.ac.in/id/eprint/417 |
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