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Phenalenyl-Based Copper(II) Catalyst for Asymmetric Henry Reaction

Mandal, Ushnish (2016) Phenalenyl-Based Copper(II) Catalyst for Asymmetric Henry Reaction. Masters thesis, Indian Institute of Science Education and Research Kokata.

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    Abstract

    A new phenalenyl-based chiral ligand, 9-N-methylamino-1-N'-(S)-(-)-α-methylbenzylamino-phenalene, has been synthesized in high yield. The reaction of CuCl2 with chiral phenalenyl-based ligand, 9-N-methylamino-1-N'-(S)-(-)-α-methylbenzylamino-phenalene in 1:1 ratio results in the formation of chiral copper complex. That complex efficiently catalyzes the C-C bond forming Henry reaction, between nitroalkane and aldehydes, with high yields (up to 90%) and moderate enantioselectivites (up to 80%).

    Item Type: Thesis (Masters)
    Additional Information: Supervisor: Dr. Swadhin K. Mandal
    Uncontrolled Keywords: Asymmetric Henry Reaction; Catalyst; Chiral Copper Complex; Chiral Ligand; Copper(II); Henry Reaction; Phenalenyl-Based Copper(II)
    Subjects: Q Science > QD Chemistry
    Divisions: Department of Chemical Sciences
    Depositing User: IISER Kolkata Librarian
    Date Deposited: 16 Aug 2016 12:44
    Last Modified: 16 Aug 2016 12:44
    URI: http://eprints.iiserkol.ac.in/id/eprint/417

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